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热带海洋环境下GFRP纤维−树脂界面早期性能研究

Characterization of early-stage performance of fiber/resin interface in GFRP exposed to tropical ocean environment

  • 摘要: 针对热带海洋环境下GFRP早期服役性能演化规律不明晰的问题,开展了原位暴露(大气、潮汐、浸泡)与加速老化(紫外、盐雾、紫外+盐雾耦合、紫外+凝露循环)相对应的对比研究。通过宏观力学测试与微观表征手段,揭示了不同环境下树脂−纤维界面粘结性能的退化规律及劣化机理。研究结果表明:GFRP筋在含紫外辐射影响的环境下,层间剪切强度均呈现先升后降的变化规律;GFRP筋的层间剪切强度受紫外+盐雾耦合环境的影响最显著,紫外+盐雾40 d试件强度下降18.19%;通过FTIR与SEM分析验证了树脂基体在后固化、水解和分子链断裂等协同作用下,纤维−树脂界面由致密状态逐渐转变为粗糙并伴随脱粘的结构特征。

     

    Abstract: The early-stage service performance evolution of glass fiber reinforced polymer (GFRP) bars in tropical marine environments remains insufficiently understood. In-situ exposure tests (atmospheric, tidal, and seawater immersion) and accelerated aging tests (ultraviolet radiation, salt spray exposure, UV+salt spray coupling, and UV+condensation cycling) were conducted in a comparative manner. Macroscopic mechanical testing combined with microstructural characterization techniques was employed to reveal the degradation behavior and deterioration mechanisms of the fiber-resin interfacial bonding under different environmental conditions, and to establish equivalence relationships between accelerated aging and in-situ exposure. The results indicate that the atmospheric environment is mainly dominated by ultraviolet radiation and condensation effects, while the tidal environment experiences enhanced effective ultraviolet irradiation due to reflection and scattering from water surfaces. In contrast, the immersion environment is primarily controlled by moisture and salt penetration. FTIR and SEM analyses further confirm that, under the combined effects of post-curing, hydrolysis, and molecular chain scission, the fiber–resin interfacial structure gradually evolves from a dense morphology to a roughened and partially debonded state. Based on the identified degradation mechanisms, three equivalence relationships—UV+condensation–atmospheric, UV–tidal, and salt spray–immersion—were established, with acceleration factors of 1.7, 1.5, and 1.3, respectively. The corresponding MAPE values were 2.25%, 2.90%, and 1.59%, demonstrating the reliability of the proposed accelerated aging approach. These findings provide a theoretical basis for durability evaluation and accelerated test design of GFRP bars in tropical marine environments.

     

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